Using Moringa Seed Peel Powder to Remove Dyes from Aqueous Solutions
DOI:
https://doi.org/10.51699/cajmns.v4i6.2164Keywords:
Adsorption, Methylene blue, Moringa seeds, DyesAbstract
Moringa seed peel powder was used to remove methylene blue dye from the aqueous solution. The surface of the Moringa seed peel powder was characterized using (FT-IR) infrared spectroscopy, (BET) surface specification, and (SEM) scanning electron microscopy. The influencing factors were studied. On adsorption, which is the amount of adsorbent, contact time, initial concentration of the dye, temperature, and acid pH to predict the optimal conditions under which the adsorption process takes place. Adsorption equilibrium and adsorption rate data were evaluated using different isotherm and kinetic models. The isotherm results showed that the Langmuir model gave better results for the studied equilibrium data. The adsorption kinetic data better follow the pseudo-second order model. Thermodynamic variables were also evaluated and the calculated parameters indicated that the adsorption process was spontaneous and exothermic in nature.
References
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2. M. Berradi et al., “Textile finishing dyes and their impact on aquatic environs,” Heliyon, vol. 5, no. 11, p. e02711, 2019.
3. A. H. Jawad, A. S. Abdulhameed, and M. S. Mastuli, “Acid-factionalized biomass material for methylene blue dye removal: a comprehensive adsorption and mechanism study,” J. Taibah Univ. Sci., vol. 14, no. 1, pp. 305–313, 2020.
4. P. O. Oladoye, T. O. Ajiboye, E. O. Omotola, and O. J. Oyewola, “Methylene blue dye: Toxicity and potential technologies for elimination from (waste) water,” Results Eng., p. 100678, 2022.
5. G. A. El Naeem, A. I. Abd-Elhamid, O. O. M. Farahat, A. A. El-Bardan, H. M. A. Soliman, and A. A. Nayl, “Adsorption of crystal violet and methylene blue dyes using a cellulose-based adsorbent from sugercane bagasse: Characterization, kinetic and isotherm studies,” J. Mater. Res. Technol., vol. 19, pp. 3241–3254, 2022.
6. M. J. Ahmed and S. K. Theydan, “Adsorptive removal of p-nitrophenol on microporous activated carbon by FeCl3 activation: equilibrium and kinetics studies,” Desalin. Water Treat., vol. 55, no. 2, pp. 522–531, 2015.
7. A. Bhatnagar and M. Sillanpää, “Utilization of agro-industrial and municipal waste materials as potential adsorbents for water treatment—a review,” Chem. Eng. J., vol. 157, no. 2–3, pp. 277–296, 2010.
8. A. Bhatnagar, M. Sillanpää, and A. Witek-Krowiak, “Agricultural waste peels as versatile biomass for water purification–A review,” Chem. Eng. J., vol. 270, pp. 244–271, 2015.
9. J. N. Edokpayi, S. S. Ndlovu, and J. O. Odiyo, “Characterization of pulverized Marula seed husk and its potential for the sequestration of methylene blue from aqueous solution,” BMC Chem., vol. 13, no. 1, pp. 1–14, 2019.
10. A. A. Ayalew and T. A. Aragaw, “Utilization of treated coffee husk as low-cost bio-sorbent for adsorption of methylene blue,” Adsorpt. Sci. Technol., vol. 38, no. 5–6, pp. 205–222, 2020.
11. Y. Bulut and H. Aydın, “A kinetics and thermodynamics study of methylene blue adsorption on wheat shells,” Desalination, vol. 194, no. 1–3, pp. 259–267, 2006.
12. O. dos Santos Escobar, C. F. de Azevedo, A. Swarowsky, M. A. Adebayo, M. S. Netto, and F. M. Machado, “Utilization of different parts of Moringa oleifera Lam. seeds as biosorbents to remove Acid Blue 9 synthetic dye,” J. Environ. Chem. Eng., vol. 9, no. 4, p. 105553, 2021.
13. N. U. Yamaguchi et al., “A review of Moringa oleifera seeds in water treatment: Trends and future challenges,” Process Saf. Environ. Prot., vol. 147, pp. 405–420, 2021.
14. A. T. Oyeyinka and S. A. Oyeyinka, “Moringa oleifera as a food fortificant: Recent trends and prospects,” J. Saudi Soc. Agric. Sci., vol. 17, no. 2, pp. 127–136, 2018.
15. Z. F. Ma, J. Ahmad, H. Zhang, I. Khan, and S. Muhammad, “Evaluation of phytochemical and medicinal properties of Moringa (Moringa oleifera) as a potential functional food,” South African J. Bot., vol. 129, pp. 40–46, 2020.
16. C. P. Sekhar, S. Kalidhasan, V. Rajesh, and N. Rajesh, “Bio-polymer adsorbent for the removal of malachite green from aqueous solution,” Chemosphere, vol. 77, no. 6, pp. 842–847, 2009.
17. Z. Bekçi, Y. Seki, and L. Cavas, “Removal of malachite green by using an invasive marine alga Caulerpa racemosa var. cylindracea,” J. Hazard. Mater., vol. 161, no. 2–3, pp. 1454–1460, 2009.
18. O. S. Bello, K. A. Adegoke, and O. O. Akinyunni, “Preparation and characterization of a novel adsorbent from Moringa oleifera leaf,” Appl. Water Sci., vol. 7, pp. 1295–1305, 2017.
19. H. Seiler, “Secondary electron emission in the scanning electron microscope,” J. Appl. Phys., vol. 54, no. 11, pp. R1–R18, 1983.
20. J. Rouquerol, P. Llewellyn, and F. Rouquerol, “Is the BET equation applicable to microporous adsorbents,” Stud. Surf. Sci. Catal, vol. 160, no. 07, pp. 49–56, 2007.
21. A. C. Gonçalves Junior, A. P. Meneghel, F. Rubio, L. Strey, D. C. Dragunski, and G. F. Coelho, “Applicability of Moringa oleifera Lam. pie as an adsorbent for removal of heavy metals from waters,” Rev. Bras. Eng. Agrícola e Ambient., vol. 17, pp. 94–99, 2013.
22. F. I. M. S. Sangor and M. A. Al-Ghouti, “Waste-to-value: Synthesis of nano-aluminum oxide (nano-γ-Al2O3) from waste aluminum foils for efficient adsorption of methylene blue dye,” Case Stud. Chem. Environ. Eng., p. 100394, 2023.
23. S. T. Nipa et al., “Adsorption of methylene blue on papaya bark fiber: Equilibrium, isotherm and kinetic perspectives,” Results Eng., vol. 17, p. 100857, 2023.
24. S. A. Obaid, “Langmuir, Freundlich and Tamkin adsorption isotherms and kinetics for the removal aartichoke tournefortii straw from agricultural waste,” in Journal of Physics: Conference Series, IOP Publishing, 2020, p. 12011.
25. R. A. Mansour, A. El Shahawy, A. Attia, and M. S. Beheary, “Brilliant green dye biosorption using activated carbon derived from guava tree wood,” Int. J. Chem. Eng., vol. 2020, pp. 1–12, 2020.
26. S. K. Lagergren, “About the theory of so-called adsorption of soluble substances,” Sven. Vetenskapsakad. Handingarl, vol. 24, pp. 1–39, 1898.
27. H. Qiu, L. Lv, B. Pan, Q. Zhang, W. Zhang, and Q. Zhang, “Critical review in adsorption kinetic models,” J. Zhejiang Univ. A, vol. 10, no. 5, pp. 716–724, 2009.
28. G. W. Kajjumba, S. Emik, A. Öngen, H. K. Özcan, and S. Aydın, “Modelling of adsorption kinetic processes—errors, theory and application,” Adv. sorption Process Appl., pp. 1–19, 2018.
29. B. H. Hameed, D. K. Mahmoud, and A. L. Ahmad, “Sorption of basic dye from aqueous solution by pomelo (Citrus grandis) peel in a batch system,” Colloids Surfaces A Physicochem. Eng. Asp., vol. 316, no. 1–3, pp. 78–84, 2008.
30. H. Huang, J. Tang, K. Gao, R. He, H. Zhao, and D. Werner, “Characterization of KOH modified biochars from different pyrolysis temperatures and enhanced adsorption of antibiotics,” RSC Adv., vol. 7, no. 24, pp. 14640–14648, 2017.
31. D. Lin et al., “Adsorption of dye by waste black tea powder: parameters, kinetic, equilibrium, and thermodynamic studies,” J. Chem., vol. 2020, pp. 1–13, 2020.
32. A. H. Jawad, Y. S. Ngoh, and K. A. Radzun, “Utilization of watermelon (Citrullus lanatus) rinds as a natural low-cost biosorbent for adsorption of methylene blue: kinetic, equilibrium and thermodynamic studies,” J. Taibah Univ. Sci., vol. 12, no. 4, pp. 371–381, 2018.
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Published
2023-12-09
How to Cite
Khalaf, I. A. W., & Al-Mahmoud, S. M. (2023). Using Moringa Seed Peel Powder to Remove Dyes from Aqueous Solutions. Central Asian Journal of Medical and Natural Science, 4(6), 943–954. https://doi.org/10.51699/cajmns.v4i6.2164
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